102.91 amu
dimer vibrational frequency = 283.9
dimer force constant = 2.44 mdyne/Å
References
"Spectroscopy of mass-selected rhodium dimers in argon matrices"
Huaiming Wang, Hanae Haouari, Robert Craig, Yifei Liu, John R. Lombardi
and D. M. Lindsay J. Chem. Phys. 106, 2101 (1997)
Abstract
The absorption (scattering depletion) spectrum and Raman spectra for
in an argon matrix prepared by the mass selected ion deposition technique
have been obtained. The absorption spectrum in the visible region shows
a single broad transition centered near 495 nm. Resonance Raman spectra
obtained by exciting with 8 visible lines (457.9 - 514.5 nm) of an argon
ion laser give a single, sharp progression with up to four Stokes transitions.
These data give we
= 283.9 (18) with wece
= 1.83 (33) , leading to an experimental
dissociation energy of 1.4 ± 0.3 eV. The Raman results are discussed
in the context of previous theoretical predictions for the dimer.
BACK