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"Resonance Raman spectroscopy of mass selected chromium trimers in an argon matrix"
Li Fang, Ben Davis, Haiyan Lu, and John R. Lombardi
J. Phys. Chem. A, 105, 9375 (2001)
Abstract
The resonance Raman spectra of mass-selected chromium trimers (Cr3) in argon matrices have been obtained. Five resonance Raman transitions were observed between 450 nm and 690 nm. Four of them are assigned to a totally symmetric (a1') vibrational progression, from which we obtain a ground state harmonic frequency of we = 432.2 cm-1 with wece = 16.3 cm-1. The other Raman line, observed at 302.0 cm-1, is assigned to the degenerate bending motion n2(e') of the triatomic metal cluster. The geometry of the ground state is that of an equilateral triangle (D3h). These results provide a value of the stretching force constant of ke = 1.91 mdyne/Å and a spectroscopic atomization energy of 0.36 eV.
Fig. 1 Resonance Raman Spectrum of Mass-Selected Chromiun Trimer